Laccase kinetics of degradation and coupling reactions
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چکیده
منابع مشابه
Conditions Optimizing and Application of Laccase-mediator System (LMS) for the Laccase-catalyzed Pesticide Degradation
A high capacity of laccase from Trametes versicolor capable of degrading pesticides has been revealed. The conditions for degrading of five selected pesticides including chlorpyrifos, chlorothalonil, pyrimethanil, atrazine and isoproturon with the purified laccases from Trametes versicolor were optimized. The results showed that the optimum conditions for the highest activity were pH at 5.0 and...
متن کاملCoupling Reactions
Coupling reactions, most prominently Heck and Suzuki couplings but also Sonogashira coupling and allylic substitution, are established catalytic transformations for the synthesis of fine chemicals. The recovery of catalytically active complexes from such coupling reactions, by the concept of covalent binding to soluble polymers, has been studied by various research groups. This research, addres...
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The reactions of nitric oxide (NO) with the oxidized and reduced forms of fungal and tree laccase, as well as with tree laccase depleted in type 2 copper, are reported. The products of the reactions were determined by NMR and mass spectroscopy, whereas the oxidation states of the enzymes were monitored by EPR and optical spectroscopy. All three copper sites in fungal laccase are reduced by NO. ...
متن کاملDegradation of azo dyes by laccase and ultrasound treatment.
The goal of this work was to investigate the decomposition of azo dyes by oxidative methods, such as laccase and ultrasound treatments. Each of these methods has strong and feeble sides. The laccase treatment showed high decolorization rates but cannot degrade all investigated dyes (reactive dyes), and high anionic strength led to enzyme deactivation. Ultrasound treatment can decolorize all tes...
متن کاملThe Kinetics and Mechanisms of Substitution Reactions of Trans-[Co(en)2CNCl]+ in Binary Mixed Solvent
The kinetics and mechanisms of the substitution reactions of trans-[Co(en)2CNCl]+ with unidentate anions, , CN¯, I¯, , Br¯ and SCN¯ in 60% v/v DMF-H2O binary solvent at 40.0±0.2 °C were studied spectrophotometrically. An Id mechanism was assigned for the replacement of chlorine by , CN¯ and I¯, an Ia one for...
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ژورنال
عنوان ژورنال: Journal of Molecular Catalysis B: Enzymatic
سال: 2005
ISSN: 1381-1177
DOI: 10.1016/j.molcatb.2005.01.005